Author: Enrico Ravera Publisher: Royal Society of Chemistry ISBN: 1788010868 Category : Science Languages : en Pages : 340
Book Description
Paramagnetic NMR is a growing technique that represents an increasingly important tool for the investigation of biomolecules. This book presents an update and overview of the paramagnetic NMR phenomena and effects as well as guidelines for practical implementation of state-of-the-art experiments. All experiments are supported by a solid theoretical foundation. Areas mentioned are the development of solid state NMR, the use of paramagnetic tags providing information on the structure and mobility of the investigated systems, and dynamic nuclear polarization to increase sensitivity. Compiled by experts in the field, this book has international appeal for researchers as well as students interested in magnetic resonance and structural biology who require experimental support and accessible information.
Author: Nicola Ann Spaldin Publisher: Cambridge University Press ISBN: 9780521016582 Category : Science Languages : en Pages : 228
Book Description
This book covers the fundamentals of magnetism and the basic theories and applications of conventional magnetic materials. In addition there is extensive discussion of novel magnetic phenomena and their modern device applications. The book starts with a review of elementary magnetostatics and magnetic materials, followed by a discussion of the atomic origins of magnetism. The properties and applications of ferro-, ferri, para-, dia- and antiferro-magnets are surveyed, and the basic theories that describe them are outlined. The final part of the book focuses on novel magnetic phenomena, and on magnetic materials in modern technological applications. Based on a course given by the author in the Materials Department at UC Santa Barbara, the book is targeted at graduate and advanced undergraduate students as well as researchers new to the field. Highly illustrated, containing numerous homework problems and worked solutions, this book is ideal for a one semester course in magnetic materials.
Author: Ivano Bertini Publisher: Elsevier ISBN: 0444634487 Category : Science Languages : en Pages : 510
Book Description
NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and Models, Second Edition is a self-contained, comprehensive reference for chemists, physicists, and life scientists whose research involves analyzing paramagnetic compounds. Since the previous edition of this book was published, there have been many advancements in the field of paramagnetic NMR spectroscopy. This completely updated and expanded edition contains the latest fundamental theory and methods for mastery of this analytical technique. Users will learn how to interpret the NMR spectra of paramagnetic molecules, improve experimental techniques, and strengthen their understanding of the underlying theory and applications. - Reflects all advances in the field in a completely updated new edition - Presents new material on self-orientation residual dipolar couplings, solid state NMR, dynamic nuclear polarization, and paramagnetic restraints for structure calculations - Includes information relevant to paramagnetic molecules, metallobiomolecules, paramagnetic compounds, and paramagnetic NMR spectroscopy - Presents specific examples of paramagnetic inorganic species and experimental techniques for structure characterization
Author: Lawrence J. Berliner Publisher: Springer Science & Business Media ISBN: 1461528860 Category : Medical Languages : en Pages : 450
Book Description
The first of a two volume set, Volume 12 provides a long-awaited compilation of NMR theory to paramagnetic molecules. International experts report the latest developments in NMR methodology as applied to strongly relaxed and shifted resonances, detail the theoretical aspects of paramagnetic shift and relaxation, and discuss the interpretive bases of these molecular properties in relation to the structure and function of various paramagnetic molecules.
Author: L. Sorin Publisher: Springer Science & Business Media ISBN: 1461586909 Category : Technology & Engineering Languages : en Pages : 268
Book Description
The authors of this contribution to the literature of resonance spectroscopy in paramagnetic systems are primarily concerned with the properties of the rare earth ions and, as such, the formal derivation of crystal field theory is set out in a manner which reflects this dominant interest. The ions of the 3d transition group are perhaps given too cursory a treatment in Chapter Two for those students of RF spectroscopy who have a somewhat less rare-earth oriented interest in the subject. Since the exam ples cited in the text do include some 3d transition ions, it is perhaps worthwhile in a preface of this sort to extend the broad theoretical concepts and group characteriza tion of Chapter Two to cover, in a somewhat more detailed manner, the derivation of the spin-Hamiltonian for this case. In Chapter Two, mention is made of the fact that for the 4f rare earth ions the spin orbit coupling energy is in general large compared to the crystal field influence of the surrounding ligand matrix. In such a case, the quantum number J is a good quantum number for the rare earth ion in question and the crystal field effects are taken into account within 1M, states. In this formulation, which is pursued in detail in this book, the effects of spin-orbit coupling have been taken care of at the very outset by the d~"ining of the 1M, states.
Author: Alessandro Bencini Publisher: Springer Science & Business Media ISBN: 3642745997 Category : Science Languages : en Pages : 299
Book Description
This book is intended to collect in one place as much information as possible on the use of EPR spectroscopy in the analysis of systems in which two or more spins are magnetically coupled. This is a field where research is very active and chemists are elbow-to-elbow with physicists and biologists in the forefront. Here, as in many other fields, the contributions coming from different disciplines are very important, but for active researchers it is sometimes difficult to follow the literature, due to differences in languages, and sources which are familiar to, e. g. , a physicist, are exotic to a chemist. Therefore, an effort is needed in order to provide a unitary description of the many different phenomena which are collected under the title. In order to define the arguments which are treated, it is useful to state clearly what is not contained here. So we do not treat magnetic phenomena in conductors and we neglect ferro- and antiferromagnetic resonance. The basic foundations of EPR spectroscopy are supposed to be known by the reader, while we introduce the basis of magnetic interactions between spins. In the first two chapters we review the foundations of exchange interactions, trying to show how the magnetic parameters are bound to the electronic structure of the interacting centers.
Author: Dariya Savchenko Publisher: Bentham Science Publishers ISBN: 168108693X Category : Science Languages : en Pages : 304
Book Description
This volume presents information about several topics in the field of electron paramagnetic resonance (EPR) study of carbon-containing nanomaterials. It introduces the reader to an array of experimental and theoretical approaches for the analysis of paramagnetic centers (dangling bonds, interface defects, vacancies, and impurities) usually observed in modern carbon-containing materials such as nanographites, graphene, disordered onion-like carbon nanospheres (DOLCNS), single-walled carbon nanotubes (SWCNTs), multi-walled carbon nanotubes (MWCNT), graphene oxide (GO), reduced graphene oxide (rGO), nanodiamonds, silicon carbonitride (SiCN) and silicon carbide (SiC) based composites and thin films. In particular, the book describes in detail: • The fundamentals of EPR spectroscopy and its application to the carbon-containing materials; • The resolution of the EPR signals from different species in carbon materials; • EPR characterization of spin dynamics in carbon nanomaterials; • Magnetic properties of DWCNTs and MWCNTs polymer composites; • EPR investigations on GO, rGO and CNTs with different chemical functionalities; • EPR spectroscopy of semiconducting SWCNTs thin films and their transistors; • In-situ EPR investigations of the oxygenation processes in coal and graphene materials; • The two-temperature EPR measurement method applied to carbonaceous solids; • Characterization of impurities in nanodiamonds and SiC nanomaterials and related size effects by CW and pulse EPR techniques; • Application of multifrequency EPR to the study of paramagnetic defects in a-Si1-xCx:H thin films and a-SiCxNy based composites. This volume is a useful guide for researchers interested in the EPR study of paramagnetic centers in the carbon-containing thin films, nanomaterials, ceramics, etc. It is also a valuable teaching tool at graduate and postgraduate levels for advanced courses in analytical chemistry, applied sciences and spectroscopy.
Author: Andrew Butterfield Publisher: Oxford University Press ISBN: 0191038660 Category : Technology & Engineering Languages : en Pages : 1055
Book Description
This popular dictionary, formerly published as the Penguin Dictionary of Electronics, has been extensively revised and updated, providing more than 5,000 clear, concise, and jargon-free A-Z entries on key terms, theories, and practices in the areas of electronics and electrical science. Topics covered include circuits, power, systems, magnetic devices, control theory, communications, signal processing, and telecommunications, together with coverage of applications areas such as image processing, storage, and electronic materials. The dictionary is enhanced by dozens of equations and nearly 400 diagrams. It also includes 16 appendices listing mathematical tables and other useful data, including essential graphical and mathematical symbols, fundamental constants, technical reference tables, mathematical support tools, and major innovations in electricity and electronics. More than 50 useful web links are also included with appropriate entries, accessible via a dedicated companion website. A Dictionary of Electronics and Electrical Engineering is the most up-to-date quick reference dictionary available in its field, and is a practical and wide-ranging resource for all students of electronics and of electrical engineering.
Author: G. N. La Mar Publisher: Elsevier ISBN: 1483272451 Category : Science Languages : en Pages : 695
Book Description
NMR of Paramagnetic Molecules: Principles and Applications is a compendium of papers that discusses the physical principles behind the technique of nuclear magnetic resonance, as well as, evaluates the scope and limitation of the applications of NMR in chemistry and biology. These papers emphasize the applications of the technique in chemistry and biochemistry where it widely used, particularlyon NMR experiments in the liquid state. Some papers describe the theoretical factors governing the resonance position and linewidth, and then also interpret magnetic resonance parameters in terms of electronic structure. Another paper investigates the gap between the mathematical complexities of earlier experiments and the operational aspects of chemical information from the spectra. Examples show studies in biochemical molecules and process in events where contact interactions are present either as a result of intrinsic molecular paramagnetism or are just induced through the addition of suitable paramagnetic probes. One paper presents the definitive and controversial results involving stereochemistry and deuterium NMR. This collection of papers will prove useful for nuclear physicists, researchers, and academicians in the field of nuclear physics.
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Author: Philip S. Callahan
Author: Enrico Ravera
Author: Nicola Ann Spaldin
Author: Ivano Bertini
Author: Lawrence J. Berliner
Author: L. Sorin
Author: Alessandro Bencini
Author: Dariya Savchenko
Author: Andrew Butterfield
Author: G. N. La Mar