A Farewell to Entropy

Author: Arieh Ben-Naim
Publisher: World Scientific
ISBN: 9812707069
Category : Science
Languages : en
Pages : 411

Book Description
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term ?entropy? with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the ?driving force? of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term ?entropy?; almost 50 years since Shannon developed the mathematical theory of ?information? ? subsequently renamed ?entropy.? In this book, the author advocates replacing ?entropy? by ?information,? a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term ?entropy.? The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur?Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the ?driving force? for which is analyzed in terms of information.

Farewell To Entropy, A: Statistical Thermodynamics Based On Information

Author: Arieh Ben-naim
Publisher: World Scientific
ISBN: 9814338281
Category : Science
Languages : en
Pages : 411

Book Description
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term “entropy” with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the “driving force” of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term “entropy”; almost 50 years since Shannon developed the mathematical theory of “information” — subsequently renamed “entropy”. In this book, the author advocates replacing “entropy” by “information”, a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term “entropy”.The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the “driving force” for which is analyzed in terms of information.

An Introduction To Statistical Thermodynamics

Author: Robert P H Gasser
Publisher: World Scientific Publishing Company
ISBN: 9813103132
Category : Science
Languages : en
Pages : 190

Book Description
Statistical thermodynamics plays a vital linking role between quantum theory and chemical thermodynamics, yet students often find the subject unpalatable.In this updated version of a popular text, the authors overcome this by emphasising the concepts involved, in particular demystifying the partition function. They do not get bogged down in the mathematical niceties that are essential for a profound study of the subject but which can confuse the beginner. Strong emphasis is placed on the physical basis of statistical thermodynamics and the relations with experiment. After a clear exposition of the distribution laws, partition functions, heat capacities, chemical equilibria and kinetics, the subject is further illuminated by a discussion of low-temperature phenomena and spectroscopy. The coverage is brought right up to date with a chapter on computer simulation and a final section which ranges beyond the narrow limits usually associated with student texts to emphasise the common dependence of macroscopic behaviour on the properties of constituent atoms and molecules.Since first published in 1974 as ‘Entropy and Energy Levels’, the book has been very popular with students. This revised and updated version will no doubt serve the same needs.

Discover Entropy And The Second Law Of Thermodynamics: A Playful Way Of Discovering A Law Of Nature

Author: Arieh Ben-naim
Publisher: World Scientific
ISBN: 9814465267
Category : Science
Languages : en
Pages : 287

Book Description
This is a sequel to the author's book entitled “Entropy Demystified” (Published by World Scientific, 2007). The aim is essentially the same as that of the previous book by the author: to present Entropy and the Second Law as simple, meaningful and comprehensible concepts. In addition, this book presents a series of “experiments” which are designed to help the reader discover entropy and the Second Law. While doing the experiments, the reader will encounter three most fundamental probability distributions featuring in Physics: the Uniform, the Boltzmann and the Maxwell-Boltzmann distributions. In addition, the concepts of entropy and the Second Law will emerge naturally from these experiments without a tinge of mystery. These concepts are explained with the help of a few familiar ideas of probability and information theory.The main “value” of the book is to introduce entropy and the Second Law in simple language which renders it accessible to any reader who can read and is curious about the basic laws of nature. The book is addressed to anyone interested in science and in understanding natural phenomenon. It will afford the reader the opportunity to discover one of the most fundamental laws of physics — a law that has resisted complete understanding for over a century. The book is also designed to be enjoyable.There is no other book of its kind (except “Entropy Demystified” by the same author) that offers the reader a unique opportunity to discover one of the most profound laws — sometimes viewed as a mysterious — while comfortably playing with familiar games. There are no pre-requisites expected from the readers; all that the reader is expected to do is to follow the experiments or imagine doing the experiments and reach the inevitable conclusions.

Statistical Mechanics

Author: B. Widom
Publisher: Cambridge University Press
ISBN: 9780521009669
Category : Science
Languages : en
Pages : 182

Book Description
This book is an introduction to statistical mechanics, intended for advanced undergraduate or beginning graduate students.

Advances in the Theory of Quantum Systems in Chemistry and Physics

Author: Philip E. Hoggan
Publisher: Springer Science & Business Media
ISBN: 9400720769
Category : Science
Languages : en
Pages : 630

Book Description
Advances in the Theory of Quantum Systems in Chemistry and Physics is a collection of 32 selected papers from the scientific contributions presented at the 15th International Workshop on Quantum Systems in Chemistry and Physics (QSCP-XV), held at Magdalene College, Cambridge, UK, from August 31st to September 5th, 2010. This volume discusses the state of the art, new trends, and the future of methods in molecular quantum mechanics and their applications to a wide range of problems in chemistry, physics, and biology. The breadth and depth of the scientific topics discussed during QSCP-XV are gathered in seven sections: I. Fundamental Theory; II. Model Atoms; III. Atoms and Molecules with Exponential-Type Orbitals; IV. Density-Oriented Methods; V. Dynamics and Quantum Monte-Carlo Methodology; VI. Structure and Reactivity; VII. Complex Systems, Solids, Biophysics. Advances in the Theory of Quantum Systems in Chemistry and Physics is written for research students and professionals in Quantum systems of chemistry and physics. It also constitutes and invaluable guide for those wishing to familiarize themselves with research perspectives in the domain of quantum systems for thematic conversion or simply to gain insight into the methodological developments and applications to physics chemistry and biology that have actually become feasible by the end of 2010.

Thermal Physics: Entropy And Free Energies (2nd Edition)

Author: Joon Chang Lee
Publisher: World Scientific Publishing Company
ISBN: 9813108142
Category : Science
Languages : en
Pages : 392

Book Description
The book aims to explain the basic ideas of thermal physics intuitively and in the simplest possible way. It is intended to make the reader feel comfortable with the ideas of entropy and of free energy. Thermal physics is prone to misunderstanding, confusion and is often overlooked. However, a good foundation is necessary to prepare the reader for advanced level studies.

Entropy for Smart Kids and their Curious Parents

Author: Arieh Ben-Naim
Publisher: Cambridge Scholars Publishing
ISBN: 1527534693
Category : Science
Languages : en
Pages : 362

Book Description
This book discusses entropy and the Second Law of Thermodynamics in such a way that everyone can understand its subject matter. Entropy is one of the most interesting concepts in physics. Although it is a well-defined concept, it is still perceived by even well-known scientists as a concept cloaked in mystery. It is also the most misused, and often abused, concept in physics. In order to understand entropy, one needs to understand the Shannon measure of information, and in order to grasp this idea, one must be familiar with some basic concepts of probability. Therefore, this book consists of three chapters: the first discusses probability, the second addresses Information Theory, and the third considers entropy and the Second Law of Thermodynamics. Readers will discover that the Second Law is nothing but a law of probability.

Discover Entropy and the Second Law of Thermodynamics

Author: Arieh Ben-Naim
Publisher: World Scientific
ISBN: 9814299758
Category : Science
Languages : en
Pages : 287

Book Description
This is a sequel to the author’s book entitled “Entropy Demystified.” The aim is essentially the same as that of the previous book by the author: to present Entropy and the Second Law as simple, meaningful and comprehensible concepts. In addition, this book presents a series of “experiments” which are designed to help the reader discover entropy and the Second Law. While doing the experiments, the reader will encounter no unexpected results, and concepts of entropy and the Second Law will emerge naturally from these experiments without a tinge of mystery. These concepts are explained with the help of a few familiar ideas of probability and a 20-question game. The main “value” of the book is to introduce entropy and the Second Law in simple language which renders it accessible to any reader who can read and is curious about the basic laws of nature. The book is addressed to anyone interested in science and in understanding natural phenomenon. It will give the reader the opportunity to discover one of the most fundamental laws of physics — a law that has resisted complete understanding for over a century. The book is also designed to be enjoyable. There is no other book of its kind (except “Entropy Demystified” by the same author) that offers the reader a unique opportunity to discover one of the most profound laws — sometimes viewed as a mysterious law — without the tinge mystery. There are no pre-requisites expected of the readers; all that the reader is expected to do is to follow the experiments or imagine doing the experiments and reach the inevitable conclusions.

A Different Thermodynamics and its True Heroes

Author: Evgeni B. Starikov
Publisher: CRC Press
ISBN: 042901452X
Category : Science
Languages : en
Pages : 872

Book Description
Modern thermodynamics is a unique but still not a logically self-consistent field of knowledge. It has a proven universal applicability and significance but its actual potential is still latent. The development of the foundations of thermodynamics was in effect non-stop but absolutely no one has any idea about this. This book is the first of its kind that will motivate researchers to build up a logically consistent field of thermodynamics. It greatly appreciates the actual depth and potential of thermodynamics which might also be of interest to readers in history and philosophy of scientific research. The book presents the life stories of the protagonists in detail and allows readers to cast a look at the whole scene of the field by showcasing a significant number of their colleagues whose works have fittingly complemented their achievements. It also tries to trigger a detailed analysis of the reasons why the actual work in this extremely important field has in effect gone astray. It comprises five chapters and introduces three scientists in the first two chapters, which are specifically devoted to the Scandinavian achievements in macroscopic thermodynamics. These introductions are novel and call for a detailed reconsideration of the field. The third chapter acquaints the readers with their fourth colleague in Germany who was working on the proper link between the macroscopic thermodynamics, kinetics, and the atomistic representation of matter. The fourth chapter brings in their fifth colleague in the United States who could formally infer the famous formula S = k * ln(W), ingeniously guessed by Ludwig Boltzmann, and thus clarify the physical sense of the entropy notion. The last chapter summarizes the above-mentioned discourses.